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Thermoset Cure Kinetics Part 11. A Mathematical Approach to Cure Kinetics Analysis

September 24, 2018 By Jeffrey Gotro 1 Comment

Guest Post by Dr. R. Bruce Prime and Dr. John Avila This post outlines the mathematical approaches to model the cure behavior and then analyze the cure data to extract kinetic parameters. We do this by utilizing equations developed in the previous post that model the cure path of autocatalytic systems like epoxy-amine. Modeling Cure Behavior For this case we developed ... [Click to Continue...]

Thermoset Cure Kinetics Part 10: Autocatalytic Equations

September 17, 2018 By Jeffrey Gotro 2 Comments

Guest Post by Dr. R. Bruce Prime and Dr. John Avila This post describes the kinetic equations used to characterize thermoset reactions that are autocatalytic in nature. The autocatalytic equations originate from a kinetic equation based on the chemistry of the epoxy-amine reaction and invoke assumptions that simplify the math. Epoxy-amine thermosets are in widespread use ... [Click to Continue...]

Thermoset Cure Kinetics; Guest Post Series

September 13, 2018 By Jeffrey Gotro 1 Comment

On Monday we provided a review of cure kinetics (Part 9) and set the stage for an exciting series on Thermoset Cure Kinetics by Dr. R. Bruce Prime and Dr. John Avila.  Over the next six weeks, the following guest posts will be presented: Thermoset Cure Kinetics Part 10: Autocatalytic Equations Thermoset Cure Kinetics Part 11: A Mathematical Approach to Kinetics ... [Click to Continue...]

Thermoset Cure Kinetics Part 9: Review of Thermoset Cure Kinetics

September 10, 2018 By Jeffrey Gotro Leave a Comment

Guest Post by Dr. R. Bruce Prime and Dr. John Avila Like cooking, thermoset curing is a time-temperature process. Kinetics addresses relationships between time and temperature. For the next seven weeks we continue the series of 8 blogs on Thermoset Cure Kinetics posted in October, November and December 2014. The previous series covered the basic concepts of kinetics, ... [Click to Continue...]

Happy Labor Day

September 3, 2018 By Jeffrey Gotro 1 Comment

Wishing all my loyal readers a safe and relaxing Labor Day weekend. I am excited to announce that next week, Dr. Bruce Prime will be back with an extensive series of guest posts on Kinetics of Thermosetting Polymers.  Dr. Prime is a former IBM colleague and Principal Consultant at InnoCentrix.  Bruce and I have collaborated on several projects including our comprehensive book ... [Click to Continue...]

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Polymer Innovation Blog

I’m Dr. Jeff Gotro and welcome to the Polymer Innovation Blog. Over the last 40 years I have been involved in polymer research, along with product and process development. I acquired invaluable experience working for IBM, AlliedSignal, Honeywell, Ablestik Labs (now Henkel) and in multiple consulting projects. In this blog, I (along with some guest contributors) will share our experiences, tips, and “tricks of the trade” to get more out of your innovation efforts and discuss new trends and technical advances in the polymer industry.
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Polymers in Electronic Packaging

polymers in electronic packaging Are you confused about what is electronic packaging? Have you ever wondered what type of polymers and polymer-based composites are used in electronics? Learn More...

Practical Tips for Curing Thermosets

practical tips for curing thermosets Have you ever had a question about the degree of cure or is your part fully cured after processing? Confused about what is gelation or how does vitrification impact thermoset curing? Learn More...

Rheology of Thermosets

rheology of thermosets Have you ever had a question about measuring the rheological properties of thermosets Didn’t know what is the right experimental approach to get the right rheological information? Learn More...

Dielectric Cure Monitoring of Thermosets

Dielectric Cure Monitoring of Thermosets Do you have a need for an in-situ cure monitor for a thermoset process but don’t know where to start? Are you confused about the terminology used in dielectric spectroscopy? Learn More...

Introduction to Biopolymers and Bioplastics

Introduction to Biopolymers and Bioplastics Would you like to know how sustainable are bio-based polymers? Or what is the market size and growth rate for bioplastics? Or have questions about the biomass supply chain? Learn More...

Thermoset Characterization

Thermoset Characterization Have you ever had a question about how to measure a physical property of a thermoset? Confused about what is gelation or how does vitrification impact thermoset curing profiles? Or wondered how to measure the glass transition temperature of an epoxy or polyester composite? Learn More...

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